REACTION OF PROPARGYL BROMIDE AND TRIMETHYLSILYLPROPARGYL IODIDE WITH METALLIC TIN, ALUMINIUM, AND ALDEHYDES OR KETONES. SELECTIVE SYNTHESIS OF β-ACETYLENE, β-TRIMETHYLSILYLACETYLENE, AND α-TRIMETHYLSILYLALLENE ALCOHOLS

DOI: 10.1246/cl.1984.1939

Source and publish data:

Chemistry Letters p. 1939 - 1942 (1984)

Update date:2022-09-26

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Authors:

Nokami, Junzo

Tamaoka, Takashi

Koguchi, Tadao

Okawara, Rokuro

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Article abstract of DOI:10.1246/cl.1984.1939

β-Acetylenic and α-allenic alcohols were synthesized selectively by the reaction of aldehydes and ketones with organotin compounds prepared by treatment of propargyl bromide or trimethylsilylpropargyl iodide with metallic tin and aluminium in a suitable solvent.

Full text of DOI:10.1246/cl.1984.1939

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