Palladium(II)-catalyzed 1,4-addition of arylboronic acids to β-arylenals for enantioselective syntheses of 3,3-diarylalkanals: a short synthesis of (+)-(R)-CDP 840

DOI: 10.1016/j.tetlet.2007.04.038

Source and publish data:

Tetrahedron Letters p. 4007 - 4010 (2007)

Update date:2022-08-05

Topics:

Authors:

Nishikata, Takashi

Yamamoto, Yasunori

Miyaura, Norio

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Article abstract of DOI:10.1016/j.tetlet.2007.04.038

1,4-Addition of arylboronic acid to trans-β-arylenals proceeded smoothly in acetone-water (10/1) at 10-25 °C in the presence of [Pd(S,S-chiraphos)(PhCN)₂](SbF₆)₂ (0.5 mol %), AgX (X = BF₄, SbF₆, 10 mo

Full text of DOI:10.1016/j.tetlet.2007.04.038

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