Studies of zoanthamine alkaloids. Enantiocontrolled construction of the tetracyclic hemi-aminal core

DOI: 10.1016/S0040-4039(98)00369-4

Source and publish data:

Tetrahedron Letters p. 2675 - 2678 (1998)

Update date:2022-08-02

Topics:

Authors:

Williams, David R.

Cortez, Guillermo S.

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Article abstract of DOI:10.1016/S0040-4039(98)00369-4

A concise enantiocontrolled synthesis of the enamine-aminal heterocyclic core found in the zoanthamine alkaloids is presented. Conjugate addition of a chiral imine provides for excellent diastereofacial selectivity in the generation of the quaternary C₉ asymmetry of 4.

Full text of DOI:10.1016/S0040-4039(98)00369-4

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