
Tetrahedron Letters p. 3845 - 3846 (1984)
Update date:2022-07-29
Topics:
Rautenstrauch, Valentin
Heating 1,1-dimethyl-2-propynyl acetate (1) with PdCl2(MeCN)2 (O.O5-0.1 mol equiv) and MeCN alone afforded (E)-2.7-dimethylocta-2,4,6-trien-3,6-diyl diacetate (2) (yield ca. 20percent) and with 1-decene (7 mol equiv) present (E)-2-methyltetradeca-2,4-dien-3-yl acetate (7) (30percent) together with 2 (12percent).
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