PHOTOINDUCED REACTIONS OF ORGANIC COMPOUNDS WITH TRANSITION METAL COMPLEXES IV. THERMAL AND PHOTOCHEMICAL REACTIONS OF PtCl62- AND PtCl42- WITH OLEFINS AND ALCOHOLS: CONVENIENT SYNTHESIS OF ?-OLEFIN COMPLEXES OF PLATINUM(II)

DOI: 10.1016/0022-328X(84)85063-9

Source and publish data:

Journal of Organometallic Chemistry p. 283 - 294 (1984)

Update date:2022-09-26

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Authors:

Shul'Pin, G. B.

Nizova, G. V.

Lederer, P.

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Article abstract of DOI:10.1016/0022-328X(84)85063-9

Olefinplatinum(II) ?-complexes can be synthesized by the following methods: (i) heating a solution of an olefin, alcohol or alkyl acetate and PtCl6^2- in acetic acid; (ii) light irradiation of a solution of PtCl6^2- and an olefin in acetone, and (iii) light irradiation of a solution of PtCl4^2- and an olefin in aqueous acetone.The possible mechanisms of the thermal and photoinduced reactions are discussed.

Full text of DOI:10.1016/0022-328X(84)85063-9

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