Tetrahedron Letters p. 4775 - 4778 (1984)
Update date:2022-07-30
Topics:
Shimagaki, Masayuki
Maeda, Tadashi
Matsuzaki, Yuji
Hori, Ishaburo
Nakata, Tadashi
Oishi, Takeshi
Reduction of α-methylthio and α-phenylthio ketones 1 with L- selectride gave syn-alcohols 2 in high stereoselectivity except when R1 was cyclohexyl group, while reduction with Zn(BH4)2 gave the isomeric anti-alcohols 3 provided R3 was a methyl group.
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