Journal of the Chemical Society. Chemical communications p. 1007 - 1008 (1984)
Update date:2022-08-04
Topics:
Ochiai, Masahito
Ukita, Tatsuzo
Nagao, Yoshimitsu
Fujita, Eiichi
1,4-Fragmentation of γ-tributylstannyl alcohols using iodosylbenzene, boron trifluoride-diethyl ether, and dicyclohexylcarbodiimide produces unsaturated carbonyl compounds; the fragmentation, combined with conjugate addition of tributylstannyl-lithium and reduction or alkylation, offers an efficient procedure for the reductive and alkylative ring opening of cyclic vinyl ketones.
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(1961)
