Synthesis and Configurations of O-Substituted Hydroxyimoyl Chlorides. Stereochemistry and Mechanism of Alkoxide Ion Substitution at the Carbon-Nitrogen Double Bond

Article abstract of DOI:10.1021/jo00207a017

An X-ray crystallographic analysis of (E)-O-methyl-p-nitrobenzohydroximoyl chloride (2b) has benn carried out to confirm the configuration of the compound.The dihedral angle between the benzene ring in 2b and the hydroximoyl chloride functional group is 5