
Journal of the Chemical Society. Perkin transactions II p. 1673 - 1680 (1984)
Update date:2022-07-30
Topics:
Happer, Duncan A. R.
The 13C n.m.r. chemical shifts of a series of meta- and para-X-substituted styrenes (X = H, NMe2, OMe, Me, F, Cl, Br, I, CF3, CO2Me, Ac, CN, NO2, NMe3+) have been determined in seven different solvents (75percent EtOH-D2O, EtOH, Me2SO, Me2CO, CDCl3, CCl4, and C6H6).The data for the side-chain carbons and for the ring carbon para- to the substituent (C6) in the meta-series have been analysed and used as a basis for assessing the effect of solvent on ?I, ?RO, ?RBA, and ?R-.
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