Macromolecules p. 6017 - 6025 (2011)
Update date:2022-08-05
Topics:
Smeets, Alfons
Willot, Pieter
De Winter, Julien
Gerbaux, Pascal
Verbiest, Thierry
Koeckelberghs, Guy
Polythiophenes with alcohol, tosylate, azide, ethynylene, carboxylic acid, and amine end groups were prepared by a combination of functionalized nickel initiators and postpolymerization reactions. The azide and ethynylene polymers were subsequently used in a click reaction to produce a conjugated block copolymer. Finally, a conjugated triblock-copolymer was synthesized by means of a chain growth polymerization initiated by a binuclear nickel initiator.
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