Journal of the Chemical Society. Perkin transactions I p. 2641 - 2647 (1984)
Update date:2022-09-26
Topics:
Katada, Tomonori
Eguchi, Shoji
Sasaki, Tadashi
1,3-Dipolar cycloaddition of adamantanethione (1) with nitrile oxides, nitrilimines, and diazoalkanes occurred smoothly to afford regioselective cycloadducts, adamantane-2-spiro-5'-(1',4',2'-oxathiazolines) (4a-f), adamantane-2-spiro-2'-(1',3',4'-thiadiazolines) (11a-d), and (21b), respectively in high yields.These results are discussed on the basis of FMO and steric effects.
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