Synthesis of pentafluorosulfanyl trifluorovinyl ether and its facile rearrangement to difluoro(pentafluorosulfanyl)acetyl fluoride

DOI: 10.1002/anie.200702425

Source and publish data:

Angewandte Chemie - International Edition p. 6626 - 6628 (2007)

Update date:2022-07-29

Topics:

Authors:

Du, Libin

Elliott, Bevan

Echegoyen, Luis

DesMarteau, Darryl D.

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Article abstract of DOI:10.1002/anie.200702425

A radical departure: A novel fluorinated vinyl ether 1 was synthesized and was found to undergo an unexpected facile rearrangement to give compound 2, which was confirmed to be a radical process by EPR spectroscopy. (Chemical Equation Presented).

Full text of DOI:10.1002/anie.200702425

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