PARTICIPATION D'UN GROUPE AMIDE A LA FORMATION DE SELS DE DIOXOLANNE-1,3 YLIUM-2; MODELE BIOMIMETIQUE DE REACTION DE PEPTIDATION

DOI: 10.1016/S0040-4020(01)91488-7

Source and publish data:

Tetrahedron p. 3399 - 3414 (1984)

Update date:2022-08-05

Topics: Protonation Cyclization reaction Nucleophilic Attack Spectroscopic Analysis Amide group

Authors:

Mestdagh, Helene

Pancrazi, Ange

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Article abstract of DOI:10.1016/S0040-4020(01)91488-7

An amide group is shown to be capable of intramolecular participation in the formation of an 1,3-dioxolan 2-ylium cation giving a tricyclic organic cation of a new type 5a,b.This cation may be considered as a model of an electrophilic intermediate which m

Full text of DOI:10.1016/S0040-4020(01)91488-7

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