SYNTHESIS OF METHYL (-)-SHIKIMATE FROM D-XYLOSE

DOI: 10.1246/cl.1985.37

Source and publish data:

Chemistry Letters p. 37 - 40 (1985)

Update date:2022-08-05

Topics: Synthesis Asymmetric synthesis Esterification HPLC (High Performance Liquid Chromatography) Chiral compound D-xylose

Authors:

Suami, Tetsuo

Tadano, Kin-ichi

Ueno, Yoshihide

Iimura, Youichi

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Article abstract of DOI:10.1246/cl.1985.37

Natural methyl (-)-shikimate has been synthesized from D-lyxose, employing a double carbon-carbon bond formation of 2,3,4-tri-O-benzyl-5-O-mesyl-D-lyxose with a dianion of dimethyl malonate as a key reaction.

Full text of DOI:10.1246/cl.1985.37

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