Chemistry Letters p. 37 - 40 (1985)
Update date:2022-08-05
Topics: Synthesis Asymmetric synthesis Esterification HPLC (High Performance Liquid Chromatography) Chiral compound D-xylose Methyl (-)-shikimate
Suami, Tetsuo
Tadano, Kin-ichi
Ueno, Yoshihide
Iimura, Youichi
Natural methyl (-)-shikimate has been synthesized from D-lyxose, employing a double carbon-carbon bond formation of 2,3,4-tri-O-benzyl-5-O-mesyl-D-lyxose with a dianion of dimethyl malonate as a key reaction.
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