A Dilithium o-Phenylenediphosphide 2 as a -)2-1,2> or 2-)2-1,2> Synthon: the X-Ray Structures of and (R = SiMe3, tmeda = 2)

DOI: 10.1039/c39920001598

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1598 - 1599 (1992)

Update date:2022-08-05

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Authors:

Hitchcock, Peter B.

Lappert, Michael F.

Yin, Ping

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Article abstract of DOI:10.1039/c39920001598

The crystalline dilithium diphosphide 2 1 reacts with H2O, SiCl3Me, or to yield rac- and meso-C6H4(PHR)2-1,2, C6H4(PR2)2-1,2, or , respectively; whereas 1 with RR-Me2C(OCHCH2OTs)2 (Ts = toluene-p-sulfonate) or SiBu^tCl3 affords or , respectively.

Full text of DOI:10.1039/c39920001598

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