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Orthometallation Reaction at a Binuclear Pyrazolyl(pz) Bridged Rhodium Compound: Synthesis and Crystal Structure Determination of Rh2(μ-pz)2Br(CO)(pcBr), pcBr = P(o-BrC6F4)Ph2

DOI: 10.1039/c39850000043

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 43 - 44 (1985)

Update date:2022-07-29

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Authors:

Barcelo, FranciscoBarcelo, Francisco

Lahuerta, PascualLahuerta, Pascual

Ubeda, M. AngelesUbeda, M. Angeles

Foces-Foces, ConcepcionFoces-Foces, Concepcion

Cano, Felix H.Cano, Felix H.

Martinez-Ripoll, MartinMartinez-Ripoll, Martin

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Article abstract of DOI:10.1039/c39850000043

The complex 2 undergoes orthometallation in refluxing toluene to give a new binuclear compound containing a rhodium-rhodium bond, Rh2(μ-pz)2(μ-pc)Br(CO)(pcBr) , which has been structurally characterized by X-ray crystallography; the complex has two pyrazolyl groups and one orthometallated phosphine bridging the two inequivalent rhodium atoms, and one phosphine ligand chelating one of the rhodium atoms via P and the bromine atom from the o-bromotetrafluorophenyl group.

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Products guided by the article

Product name:(Rhodium-I(pyrazolyl)(carbonyl)(P(o-BrC6F4)(C6H5)2))2

Cas No:96411-10-8

96411-10-8

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