Palladium-catalysed carbonyl allylation by 2-methylenepropane-1,3-diol

DOI: 10.1039/cc9960001585

Source and publish data:

Chemical Communications p. 1585 - 1586 (1996)

Update date:2022-07-29

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Authors:

Masuyama, Yoshiro

Kagawa, Masaaki

Kurusu, Yasuhiko

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Article abstract of DOI:10.1039/cc9960001585

2-Methylenepropane-1,3-diol first allylates an aldehyde exclusively at the allylic alcohol moiety at room temperature and then, at 50°C, allylates another aldehyde also at the allylic alcohol moiety, in the presence of a catalytic amount of PdCl₂(PhCN)₂ with tin(II) chloride.

Full text of DOI:10.1039/cc9960001585

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