Tetrahedron Letters p. 1441 - 1444 (1985)
Update date:2022-09-26
Topics:
Glock, Volker
Wette, Michael
Klaerner, Frank-Gerrit
Trans-bicyclo<6.1.0>nonatriene 1 isomerizes thermally to the unknown 3,4-homoheptafulvene 2.A degenerate cyclopropane-walk-rearrangement detected with the aid of opt.-act.-1a precedes the structural isomerization.In both processes diradical exo-7 is considered to be an intermediate.
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