Bulletin of the Chemical Society of Japan p. 1376 - 1380 (1980)
Update date:2022-08-05
Topics:
Nishiura, Kazuo
Tagano, Tsutomu
Wada, Yasuo
Tanimoto, Shigeo
Okano, Masaya
The reaction of olefins with chloromethoxymethane (CMM) and excess formic acid in ether, in the presence of ZnCl2 or HgCl2, affored mainly four products, 1-chloro- and 1-formyloxy-2-(formyloxymethyl)alkanes, and 3,5-dialkyl-4-chloro- and 3,5-dialkyl-4-(formyloxy)tetrahydropyrans, in various yields.In the case of styrene, the chief products were limited to the former two.Similar products were obtained from 1-chloro-1-ethoxyethane(CEE), but their yields were quite low.
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Doi:10.1135/cccc19932977
(1993)Doi:10.1021/jo00216a006
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(2002)Doi:10.1016/S0040-4039(00)61921-4
(1985)Doi:10.1016/S0040-4039(00)61870-1
(1985)Doi:10.1021/acs.orglett.9b01990
(2019)
