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Photo-oxidation of Alcohols by Hexachlorometalate(IV) Ions (M = Pt, Pd, or Ir): Spin Trapping and Matrix Isolation Electron Spin Resonance Studies

DOI: 10.1039/DT9890001237

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1237 - 1240 (1989)

Update date:2022-08-05

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Authors:

Fadnis, Anand G.Fadnis, Anand G.

Kemp, Terence J.Kemp, Terence J.

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Article abstract of DOI:10.1039/DT9890001237

Spin-trapping studies reveal that whereas the mild (λ > 380 nm) photolysis of ions 2- (M = Pd, Pt, or Ir) in alcohol (RCH2OH)-water mixtures leads invariably to R<*>HOH, in pure alcoholic media many of the oxidations lead to RCH2<*>.Prolonged, wide-band photolysis leads to the production of H atoms.At 77 K, wide-band photolysis leads to the production of platinum(III) and palladium(III) centres, identifies by their g<*> features, in addition to the expected C-centred organic radicals.

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