Tetrahedron p. 4795 - 4806 (1986)
Update date:2022-07-31
Topics:
Taran, M.
Delmond, B.
The action of borontrifluoride etherate on diterpenic-8,9 epoxides has been studied.We report a rearrangement of tetrasubstituted epoxide leading to new tetracyclic diterpene skeletons.The nature of the bicyclo<3.2.1>octane moiety constituting the C/D ring system means that these new compounds could be related to stemodane and stemarane diterpenes.These rearrangements could provide a chemical test for the biosynthesis of aphidicolin derivatives.
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