A GENERAL METHOD FOR THE STEREOSELECTIVE CONSTRUCTION OF DES-AB-CHOLESTANES. A FIRST TOTAL SYNTHESIS OF (+)-8α-PHENYLSULFONYL-DES-AB-CHOLESTANE

DOI: 10.1246/cl.1985.259

Source and publish data:

Chemistry Letters p. 259 - 262 (1985)

Update date:2022-08-04

Topics:

Authors:

Nemoto, Hideo

Kurobe, Hiroshi

Fukomoto, Keiichiro

Kametani, Tetsuji

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Article abstract of DOI:10.1246/cl.1985.259

(+)-8α-Phenylsulfonyl-des-AB-cholestane, a potential intermediate of vitamin D3, was stereoselectively synthesized from (-)-indanone derivative possessing the required chiralities, at the C¹³, C¹⁴, C¹⁷, and C²⁰

Full text of DOI:10.1246/cl.1985.259

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