Bimetallic Systems. Part 8. Heterobimetallic Di-isonitrile or Isonitrile - Carbonyl Complexes of Rhodium or Iridium bridged to Silver or Gold by Ph2PCH2PPh2

DOI: 10.1039/DT9850000511

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 511 - 516 (1985)

Update date:2022-07-31

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Authors:

Langrick, C. Richard

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9850000511

Treatment of t)4(μ-dppm)2>Cl2 (M=Rh or Ir, dppm=Ph2PCH2PPh2) with dppm gave labile systems at 20 deg C. 31P-<1H> N.m.r. spectroscopy at -60 deg C showed complete conversion to the tris-monodentate dppm complexes t)2(dp

Full text of DOI:10.1039/DT9850000511

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