Tetrahedron Letters p. 1425 - 1428 (1985)
Update date:2022-08-05
Topics:
Block, Eric
Wall, Alan
Fluorodesilylation of trimethylsilylmethanesulfinyl chloride 4 in the presence of cyclopentadiene gives 2-thiabicyclo<2.2.1>hept-5-ene endo-2-oxide, 5; in a like manner 1-trimethylsilylalkanesulfonic anhydrides afford endo- and exo-3-alkyl-2-thiabicyclo<2.2.1>hept-5-ene 2,2-dioxides, with the endo isomer predominating.Sulfine and alkyl sulfenes are invoked.
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Doi:10.1016/S0040-4020(01)96470-1
(1985)Doi:10.1021/jo01059a047
(1962)Doi:10.1021/jo01047a055
(1963)Doi:10.1055/s-1986-31807
(1986)Doi:10.1016/S0277-5387(00)84510-6
(1985)Doi:10.1007/s10593-008-0060-2
(2008)
