Formation and Uses of the Dianion Formally Produced by Conjugate Addition of Bis(phenylthio)methyl Dianion to Cyclohex-2-en-1-one. Configurations and Conformations of the Products of Conjugate Addition of Tris(phenylthio)methyllithium to Carvone.

DOI: 10.1021/jo00218a005

Source and publish data:

Journal of Organic Chemistry p. 3266 - 3269 (1985)

Update date:2022-08-03

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Authors:

Cohen, Theodore

Yu, Lin-Chen

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Article abstract of DOI:10.1021/jo00218a005

When the enolate anion formed by the addition of tris(phenylthio)methyllithium to 2-cyclohexen-1-one is treated at -50 deg C with sec-butyllithium, the enolate thioacetal dianion 3 is generated.The latter forms useful compounds by the attack of electrophi

Full text of DOI:10.1021/jo00218a005

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