Formation and Uses of the Dianion Formally Produced by Conjugate Addition of Bis(phenylthio)methyl Dianion to Cyclohex-2-en-1-one. Configurations and Conformations of the Products of Conjugate Addition of Tris(phenylthio)methyllithium to Carvone.

DOI: 10.1021/jo00218a005

Source and publish data:

Journal of Organic Chemistry p. 3266 - 3269 (1985)

Update date:2022-08-03

Topics:

Authors:

Cohen, Theodore

Yu, Lin-Chen

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00218a005

When the enolate anion formed by the addition of tris(phenylthio)methyllithium to 2-cyclohexen-1-one is treated at -50 deg C with sec-butyllithium, the enolate thioacetal dianion 3 is generated.The latter forms useful compounds by the attack of electrophi

Full text of DOI:10.1021/jo00218a005

Products guided by the article

Product name:(2R,3S,5R)-3-(Bis-phenylsulfanyl-methyl)-5-isopropenyl-2-methyl-cyclohexanone

Cas No:97336-64-6

R&D Labs maybe for 97336-64-6

Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China

Relevant to this article

α-Arylamino Diazoketones: Diazomethane-Loading Controlled Synthesis, Spectroscopic Investigations, and Structural X-ray Analysis

Doi:10.1021/acs.joc.7b03134
(2018)
Cloning, mechanistic and functional analysis of a fungal sterol C24-methyltransferase implicated in brassicasterol biosynthesis

Doi:10.1016/j.bbalip.2010.06.007
(2010)
STEREOSELECTIVE FORMATION OF (E)-1-ALKENYL ETHERS. THE COUPLING REACTION OF 1,3- OR 3,3-DIETHOXY-1-PROPENE WITH GRIGNARD REAGENTS CATALYZED BY NICKEL-PHOSPHINE COMPLEX

Doi:10.1246/cl.1985.351
(1985)
Convenient syntheses of 9-[4-hydroxy-3-(hydroxymethyl)butyl]guanine (penciclovir) and 9-[4-acetoxy-3-(acetoxymethyl)butyl]-2-amino-9h-purine (famciclovir)

Doi:10.1016/S0040-4020(99)00169-6
(1999)
The Octant Rule. 15. Antioctant Effects: Synthesis and Circular Dichroism of 2-exo- and 2-endo-Alkylbicyclo<2.2.1>heptan-7-ones and -bicyclo<3.2.1>octan-8-ones

Doi:10.1021/jo00220a037
(1985)
Cyclobutanone-enamines: Synthesis and reactions of N-(1-cyclobutenyl)piperidine

Doi:10.1002/ardp.19853180715
(1985)

Article Doi