An Approach to Quassimarin Based on an Exo-Selective Intramolecular Diels-Alder Reaction

DOI: 10.1021/jo00220a064

Source and publish data:

Journal of Organic Chemistry p. 3950 - 3951 (1985)

Update date:2022-08-04

Topics:

Authors:

Schlessinger, R.H.

Wong, J.W.

Poss, M.A.

Springer, James P.

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Article abstract of DOI:10.1021/jo00220a064

A novel exo-selective intramolecular Diels-Adler reaction is used to secure the preparation of the tricyclic adduct 2, a material that contains three of the rings and five of the stereogenic centers present in the bitter principal quassimarin.

Full text of DOI:10.1021/jo00220a064

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