SYNTHETIC STUDIES TOWARD TO 1α-HYDROXYVITAMIN D3 --- STEREOSELECTIVE SYNTHESIS OF (+/-)-(Z)-2-(3β,5α-DIHYDROXY-2-METHYLENECYCLOHEXYLIDENE)ETHYLIDENECYCLOHEXANE

DOI: 10.1016/S0040-4039(00)88315-X

Source and publish data:

Tetrahedron Letters p. 4257 - 4260 (1983)

Update date:2022-08-04

Topics:

Authors:

Nemoto, Hideo

Wu, Xiao-Ming

Kurobe, Hiroshi

Ihara, Masataka

Fukumoto, Keiichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88315-X

As a model experiment for a synthesis of 1α-hydroxyvitamin D₃, the title compound (19) was stereoselectively synthesized via the solvolysis of (+/-)-2-hydroxy-2-<(3β-methoxymethoxy-2-methylenebicyclo<3.1.0>hexane)-1>ethylidenecyclohexane (15).

Full text of DOI:10.1016/S0040-4039(00)88315-X

Products guided by the article

Product name:(+/-)-α-cyclohexylidenemethyl-3-methoxymethoxy-2-methylenebicyclo<3.1.0>hexane-1-methanol

Cas No:98758-87-3

R&D Labs maybe for 98758-87-3

SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Xi'an HO-SHINE Bio-Technology Co., Ltd

Contact:+86 (29) 8248-5435/18292020086

Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China
Golden Union Agrochemical Import and Export Co., Ltd.

Contact:86-755-23910527

Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)

Contact:051989185693

Address:NO 217 huangshan Rd ,Changzhou

Relevant to this article

New Method for Preparation of Superoxide Ion by Use of Amino Oxide

Doi:10.1021/jo00225a081
(1985)
A Novel Three-Step Synthesis of a Pyrrolo<3,2-d>pyrimidine C-Nucleoside

Doi:10.1021/jo00357a021
(1986)
SELECTIVITY AND CHARGE TRANSFER IN PHOTOREACTIONS OF ARENES WITH OLEFINS 1. SUBSTITUTION VERSUS CYCLOADDITION

Doi:10.1016/S0040-4020(01)96635-9
(1985)
Formylation Products of Thioamides; Part 11. A Novel Route to Substituted 2-Aminothiophenes by the Reaction of S-Alkylated Thioamides with Carboxylic Acid Derivatives

Doi:10.1055/s-1985-31223
(1985)
Doi:10.1021/jo00821a024
(1971)
Structure-based design and synthesis of phosphinate isosteres of phosphotyrosine for incorporation in Grb2-SH2 domain inhibitors. Part 2

Doi:10.1016/S0960-894X(00)00476-5
(2000)

Article Doi