SYNTHETIC STUDIES TOWARD TO 1α-HYDROXYVITAMIN D3 --- STEREOSELECTIVE SYNTHESIS OF (+/-)-(Z)-2-(3β,5α-DIHYDROXY-2-METHYLENECYCLOHEXYLIDENE)ETHYLIDENECYCLOHEXANE

DOI: 10.1016/S0040-4039(00)88315-X

Source and publish data:

Tetrahedron Letters p. 4257 - 4260 (1983)

Update date:2022-08-04

Topics:

Authors:

Nemoto, Hideo

Wu, Xiao-Ming

Kurobe, Hiroshi

Ihara, Masataka

Fukumoto, Keiichiro

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Article abstract of DOI:10.1016/S0040-4039(00)88315-X

As a model experiment for a synthesis of 1α-hydroxyvitamin D₃, the title compound (19) was stereoselectively synthesized via the solvolysis of (+/-)-2-hydroxy-2-<(3β-methoxymethoxy-2-methylenebicyclo<3.1.0>hexane)-1>ethylidenecyclohexane (15).

Full text of DOI:10.1016/S0040-4039(00)88315-X

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