Tetrahedron Letters p. 4257 - 4260 (1983)
Update date:2022-08-04
Topics:
Nemoto, Hideo
Wu, Xiao-Ming
Kurobe, Hiroshi
Ihara, Masataka
Fukumoto, Keiichiro
As a model experiment for a synthesis of 1α-hydroxyvitamin D3, the title compound (19) was stereoselectively synthesized via the solvolysis of (+/-)-2-hydroxy-2-<(3β-methoxymethoxy-2-methylenebicyclo<3.1.0>hexane)-1>ethylidenecyclohexane (15).
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(1985)Doi:10.1021/jo00821a024
(1971)Doi:10.1016/S0960-894X(00)00476-5
(2000)