Synthesis and Characterisation of a Triple Cluster of Gold and Boron

DOI: 10.1039/c39850000819

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 819 - 820 (1985)

Update date:2022-09-26

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Authors:

Wynd, Andrew J.

Robins, Suzanne E.

Welch, Dorothy A.

Welch, Alan J.

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Article abstract of DOI:10.1039/c39850000819

Reaction of B10H14 with Et3PAuMe affords the triple cluster <(H12B10Au)(AuPEt3)4(AuB10H12)>, and with Cy3PAuMe (Cy = cyclohexyl) the substituted complex is isolated; a mechanism for the formation of the triple cluster is proposed.

Full text of DOI:10.1039/c39850000819

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