METALLORGANISCHE VERBINDUNGEN DES IRIDIUMS UND RHODIUMS. XXV. DARSTELLUNG, SPEKTROSKOPIE UND STRUKTURANALYSE EINIGER (2-6-η-1-OXOCYCLOHEXADIENYL)RHODIUM(I)-KOMPLEXE DES TYPS (η5-2,6-t-Bu2-4-MeC6H2O)RhL2

Article abstract of DOI:10.1016/0022-328X(85)80018-8

The interaction of 2,6-t-Bu2-4-MeC6H2OLi with several chlororhodium(I) complexes gave the compounds (2,6-t-Bu2-4-MeC6H2O)RhL2 (2 L=CO, PPh3 (I); 2 PPh3 (II); 2 C2H4 (III); cyclo-C8H12 (IV)) containing the phenoxide ion as an η⁵-bonded oxocycloh