INTERACTION OF CH3MgI WITH β-DICARBONYL COMPOUNDS

DOI: 10.1016/0022-328X(85)87278-8

Source and publish data:

Journal of Organometallic Chemistry p. 201 - 206 (1985)

Update date:2022-08-05

Topics: NMR spectroscopy Nucleophile Organic synthesis Product Spectroscopic Analysis Chemical Reaction β-dicarbonyl compounds Grignard Reagent Reactant Interaction

Authors:

Polivin, Yu. N.

Postnov, V. N.

Sazonova, V. A.

Zagorevsky, D. V.

Nekrasov, Yu. S.

Kharchevnikov, A. P.

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Article abstract of DOI:10.1016/0022-328X(85)87278-8

The reaction of CH3MgI with the ferrocene-containing α-monosubstituted β-dicarbonyl compounds is studied; a general reaction scheme is proposed.The addition reaction to a carbonyl group, the enolization and the C_α-C_β-cleavage prove to be non-specific by D-labelling.

Full text of DOI:10.1016/0022-328X(85)87278-8

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Product name:C₅H₅FeC₅H₄CH(C₆H₅)CH(C(OH)(CH₃)2)CO₂C₂H₅

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