INTERACTION OF CH3MgI WITH β-DICARBONYL COMPOUNDS

DOI: 10.1016/0022-328X(85)87278-8

Source and publish data:

Journal of Organometallic Chemistry p. 201 - 206 (1985)

Update date:2022-08-05

Topics: NMR spectroscopy Nucleophile Organic synthesis Product Spectroscopic Analysis Chemical Reaction β-dicarbonyl compounds Grignard Reagent Reactant Interaction

Authors:

Polivin, Yu. N.

Postnov, V. N.

Sazonova, V. A.

Zagorevsky, D. V.

Nekrasov, Yu. S.

Kharchevnikov, A. P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(85)87278-8

The reaction of CH3MgI with the ferrocene-containing α-monosubstituted β-dicarbonyl compounds is studied; a general reaction scheme is proposed.The addition reaction to a carbonyl group, the enolization and the C_α-C_β-cleavage prove to be non-specific by D-labelling.

Full text of DOI:10.1016/0022-328X(85)87278-8

Products guided by the article

Product name:C₅H₅FeC₅H₄CH(C₆H₅)CH(C(OH)(CH₃)2)CO₂C₂H₅

Cas No:99326-59-7

R&D Labs maybe for 99326-59-7

Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Hefei Lifeon Pharmaceutical Co., Ltd.

Contact:+86-551-65328450

Address:No522 Wangjiang West Road
Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China

Relevant to this article

SODIUM IODIDE/BORON TRIFLUORIDE ETHERATE: A MILD REAGENT SYSTEM FOR THE CONVERSION OF ALLYLIC AND BENZYLIC ALCOHOLS INTO CORRESPONDING IODIDES AND SULFOXIDES INTO SULFIDES

Doi:10.1016/S0040-4039(00)98145-0
(1985)
BASENINDUZIERTE UMLAGERUNGEN VON 3,9 DIOXATRICYCLO<3.3.1.0^2,4>NONAN-7-ONEN ZU m-HYDROXYPHENYLCARBONYL-VERBINDUNGEN

Doi:10.1016/S0040-4020(01)96563-9
(1985)
Synthesis and optical properties of 2'-deoxy-8,2'-methanoguanosine

Doi:10.1248/cpb.37.298
(1989)
A simple synthesis of 1,3-dialkylpyrido[2,3-d]pyrimidines

Doi:10.1248/cpb.33.1375
(1985)
Intramolecular Photocycloaddition of the C=C Double Bond to the C<*>N Triple Bond Resulting in the Formation of a Novel Cyclic System

Doi:10.1246/bcsj.67.1769
(1994)
Triethylborane-induced bromine atom-transfer radical addition in aqueous media: Study of the solvent effect on radical addition reactions

Doi:10.1021/jo010652l
(2001)

Article Doi