
Journal of Organometallic Chemistry p. 201 - 206 (1985)
Update date:2022-08-05
Topics: NMR spectroscopy Nucleophile Organic synthesis Product Spectroscopic Analysis Chemical Reaction β-dicarbonyl compounds Grignard Reagent Reactant Interaction
Polivin, Yu. N.
Postnov, V. N.
Sazonova, V. A.
Zagorevsky, D. V.
Nekrasov, Yu. S.
Kharchevnikov, A. P.
The reaction of CH3MgI with the ferrocene-containing α-monosubstituted β-dicarbonyl compounds is studied; a general reaction scheme is proposed.The addition reaction to a carbonyl group, the enolization and the Cα-Cβ-cleavage prove to be non-specific by D-labelling.
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