Journal of Organic Chemistry p. 5615 - 5619 (1985)
Update date:2022-07-29
Topics:
Levy, Joseph B.
Sterling, Doreen M.
The reaction of fluoroxytrifluoromethane (FTM) with a group of ring-substituted styrenes has been studied.Reaction products have been determined, and relative rates for addition to the double bond have been measured by a competition method.The data give a straight line when plotted as log (k/kH)vs.Hammett ? values with a ρ of -2.48.A similar plot vs. ?+ gave less satisfactory agreement with linearity and a ρ of 2.18.A mechanism is proposed in which a spin-paired free-radical pair is formed that is converted by electron transfer into an ion pair.
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