Journal of Organic Chemistry p. 5543 - 5545 (1985)
Update date:2022-07-30
Topics:
Grimm, Erich L.
Zschiesche, Ruth
Reissig, Hans-Ulrich
2-Alkenyl-substituted methyl 2-siloxycyclopropanecarboxylates 3a, 3b, and 6 - easily available from the corresponding silyl enol ether - react with a variety of O-, N-, S-, and C-nucleophiles under mild acidic or basic conditions providing polyfunctionalized products 7-19 in good to excellent yields via 1,4-addition to vinyl ketones formed in situ.Due to the versatility of the nitro group, nitroalakne, adducts 15-19 are of special interest for further transformations.
View MoreDalian RSD International Trade Co.,Ltd.(expird)
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
SuZhou Bichal Biological Technology CO.,LTD
Contact:+86-512-68051130
Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Contact:+ 86 512 52491118
Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Contact:+1 (647) 918 5848
Address:2343 BRIMLEY RD., Suite 250
Contact:+86-021-6989-5597
Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
Doi:10.1248/cpb.33.3738
(1985)Doi:10.1021/jo00352a017
(1986)Doi:10.1016/j.tet.2018.02.031
(2018)Doi:10.1021/jm00153a001
(1986)Doi:10.1016/S0040-4020(01)86746-6
(1988)Doi:10.1248/cpb.33.2122
(1985)
