Journal of Organic Chemistry p. 81 - 87 (1986)
Update date:2022-08-05
Topics: Chiral Catalyst Chemo-selective Organometallic reagents Stereoselective Regioselective
Pyne, Stephen G.
The chiral vinyl sulfoximines 1 and 2 (R' = C6H5, CH3, n-Bu, C6H5CH2CH2) have been prepared; they undergo conjugate addition reactions with organometallic reagents with high asymmetric induction.These conjugate addition adducts have been converted to chiral 3-alkylalkanoic acids in high enantiomeric excess (>90percent)
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