Journal of Organometallic Chemistry p. 125 - 132 (1988)
Update date:2022-08-02
Topics:
Rao, S. Achyutha
Periasamy, M.
The reduction of Cp2MCl2 (M=Ti or Zr) with Grignard grade magnesium and 1,2-dibromoethane in THF at 0 deg C gives the corresponding metallocene-ethylene complexes along with hydride species, as indicated by the reaction with diphenylacetylene to give 1,2-diphenyl-(E)-l-butene.The reactions of the Cp2ZrCl2/1,2-dibromobenzene/Mg system in THF with diphenylacetylene and norbornene are also described.
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