Chemistry Letters p. 809 - 812 (1985)
Update date:2022-08-04
Topics:
Mukaiyama, Teruaki
Yura, Takeshi
Iwasawa, Nobuharu
A convenient method for the stereoselective synthesis of cis-α,β-epoxyesters and aldehydes is established according to the Sn(OTf)2 mediated cross aldol reaction between α-bromo-α'-silyloxyketone and aldehyde.The reaction is applied to the stereoselective synthesis of 2-amino-2-deoxy-D-arabinitol.
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