STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXYESTERS AND ALDEHYDES VIA DIVALENT TIN ENOLATE. A SYNTHESIS OF 2-AMINO-2-DEOXY-D-ARABINITOL

DOI: 10.1246/cl.1985.809

Source and publish data:

Chemistry Letters p. 809 - 812 (1985)

Update date:2022-08-04

Topics:

Authors:

Mukaiyama, Teruaki

Yura, Takeshi

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1985.809

A convenient method for the stereoselective synthesis of cis-α,β-epoxyesters and aldehydes is established according to the Sn(OTf)2 mediated cross aldol reaction between α-bromo-α'-silyloxyketone and aldehyde.The reaction is applied to the stereoselective synthesis of 2-amino-2-deoxy-D-arabinitol.

Full text of DOI:10.1246/cl.1985.809

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