PHYSICAL AND THERMODYNAMIC PROPERTIES FOR NOVEL C14 UNSATURATED ALDEHYDES AND C16 SATURATED AMINES.

Article abstract of DOI:10.1021/je00048a034

Various group contribution methods and thermodynamic correlating equations were used to develop physical and thermodynamic properties for 28 branched isomeric C//1//4 unsaturated aldehydes and 28 isomeric C//1//6 amines derived from these aldehydes, the majority of which represent novel compositions. The particular properties that were derived include normal boiling temperatures, critical constants, vapor pressures, liquid densities, liquid heat capacities, and various ideal gas properties. The experimental results were in good agreement with most of the independently derived properties, which supports the accuracy of the estimation techniques and their utility for engineering applications involving these compounds.