Catalysis of Aerobic C-C Bond Cleavage of 1,2-Bis(4-methoxyphenyl)ethane-1,2-diol by meso-Tetraphenylporphyrinatoiron(III). A Model System for Cytochrome P-450SCC-dependent Glycol Cleavage

DOI: 10.1039/c39850000381

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 381 - 383 (1985)

Update date:2022-08-17

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Authors:

Okamoto, Tadashi

Sasaki, Ken

Shimada, Mikio

Oka, Shinzaburo

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Article abstract of DOI:10.1039/c39850000381

Catalytic cleavage of 1,2-bis(4-methoxyphenyl)ethane-1,2-diol (1a) by chloro(meso-tetraphenylporphyrinato)iron(III) in the presence of N-benzyl-3-carbamoyl-1,4-dihydropyridine under molecular oxygen at room temperature yielded exclusively 4-methoxybenzaldehyde, reproducing most features of the C-C bond cleavage of a vicinal diol catalysed by cytochrome P-450_SCC.

Full text of DOI:10.1039/c39850000381

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