Tetrahedron Letters p. 293 - 296 (1984)
Update date:2022-08-10
Topics:
Kauffmann, Thomas
Bisling, Monika
Alkyl Mn(II) compounds react like alkyl Cu(I) compounds specifically or highly selectively with cyclohex-2-enone(1) to give 3-alkylhexanones (Alk = Me, Bu) in medium or good yields.By reacting with oxiranes corresponding alkenes are produced, a reaction not observed so far with alkyl Cu(I) reagents.
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