Bulletin of the Chemical Society of Japan p. 951 - 952 (1983)
Update date:2022-08-11
Topics:
Izawa, Yasuji
Ishiguro, Katsuhiro
Tomioka, Hideo
Photolysis of trichloroacetamide in nondegassed methanol gave methyl oxanilate (13-44percent), along with carbamate (3-20percent) and amine (4-12percent).Similar irradiation of other trichloroacetylderivatives of aliphatic ketone, aldehyde, and acetate afforded only radical product.The results are interpreted in terms of the mechanism involving electron transfer of the radical pair.
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(1974)
