Tetrahedron Letters p. 4375 - 4378 (1989)
Update date:2022-08-11
Topics:
Sato, Kazuhiko
Kira, Mitsuo
Sakurai, Hideki
Various organotrifluorosilanes react with trimethylamine-N-oxide without catalyst to give the corresponding alcohols in high yields under mild conditions.Stereospecific nature of the reaction is suggestive of the involvment of intramolecular 1,2-organic-group migration from hypercoordinate silicon to oxygen.
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