New synthetic 'tricks'. a novel one-pot procedure for the conversion of primary nitro groups into aldehydes

DOI: 10.1016/S0040-4039(00)88528-7

Source and publish data:

Tetrahedron Letters p. 7499 - 7500 (1990)

Update date:2022-08-30

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Authors:

Urpi, Feelix

Vilarrasa, Jaume

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Article abstract of DOI:10.1016/S0040-4039(00)88528-7

Two tin(II) complexes, Sn(SPh)₃^- and Sn(C₄H₄O₆)₂^2-, besides NaHSO₃, are involved in a procedure developed for the rapid transformation at pH 5-6 of R-CH₂-NO₂ into R-CHOH-SO₃Na, from which the desired aldehydes have been isolated in 80-91% overall yields. Thus, a new alternative to the Nef traction is now in hand.

Full text of DOI:10.1016/S0040-4039(00)88528-7

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New synthetic 'tricks'. a novel one-pot procedure for the conversion of primary nitro groups into aldehydes

DOI: 10.1016/S0040-4039(00)88528-7

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(00)88528-7

Full text of DOI:10.1016/S0040-4039(00)88528-7

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