
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 33 - 36 (1991)
Update date:2022-08-12
Topics:
Kushch, S. D.
The kinetics of hydrogenation of nitrobenzene in aprotic media was studied, and a scheme of the mechanism and a kinetic equation, corresponding to it, for the initial reaction rate are proposed.High selectivity with respect to N-phenylhydroxylamine is apparently due to the aprotic nature and donor properties of the solvent and also to the functioning of the catalyst as a unique "hydrogen electrode."
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