Tetrahedron Letters p. 7941 - 7944 (1996)
Update date:2022-08-11
Topics:
Arterburn, Jeffrey B.
Perry, Marc C.
A mild, efficient method for the catalytic reduction of sulfoxides to sulfides with triphenylphosphine and the catalyst ReOCl3(PPh3)2 (I) is reported. Aryl sulfoxides are reduced faster than alkyl, and the reaction is successful for sterically hindered sulfoxides and those with common organic functional groups.
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