Syn-oxidative cyclizations of trishomoallylic alcohols: Stereoselective and stereospecific synthesis of trans-tetrahydropyranyl alcohols

DOI: 10.1016/S0040-4039(97)10005-3

Source and publish data:

Tetrahedron Letters p. 7683 - 7686 (1997)

Update date:2022-08-11

Topics:

Authors:

McDonald, Frank E.

Singhi, Aatur D.

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Article abstract of DOI:10.1016/S0040-4039(97)10005-3

Trifluoroacetylperrhenate promotes the hydroxyl-directed syn-oxidative cyclization of trishomoallylic alcohols. The cyclization reaction is highly stereospecific and stereoselective, providing a novel and efficient synthesis of trans-2,6-disubstituted tetrahydropyranyl alcohols.

Full text of DOI:10.1016/S0040-4039(97)10005-3

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