Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3657 - 3666 (1986)
Update date:2022-08-17
Topics:
Okuhara, Toshio
Tanaka, Ken-ichi
Neither the adsorption nor the reduction of nitrogen monoxide occurs at 360 degC on pure carbon, but significant reduction of NO, giving N2 and CO2, proceeds on potassium-doped carbons.The uptake of NO on carbon is increased markedly by doping potassium salts and the adsorbed NO undergoes decomposition and/or desorption giving N2O (25-250 degC), NO (250-400 degC) and CO2 (400 degC) in vacuum.Isotope labelling experiments using 15NO and N2(18)O suggest that the N2O is produced by the decomposition of (NO)2(a) and that the NO and CO2 are the predominant species during the reaction of NO on K-doped carbon, and NO2(a) suppresses the reaction of NO with carbon.
Doi:10.1016/j.ejmech.2015.04.036
(2015)Doi:10.1002/ejoc.201800391
(2018)Doi:10.1016/j.tetasy.2013.05.002
(2013)Doi:10.1111/j.1151-2916.2003.tb03331.x
(1887)Doi:10.1007/s00706-019-02529-w
(2020)Doi:10.1055/s-1986-31862
(1986)
