Journal of Physical Chemistry p. 4265 - 4269 (1987)
Update date:2022-08-30
Topics:
Gilbert, J. V.
Wu, X. L.
Stedman, D. H.
Coombe, R. D.
Spectra and time profiles of the emission resulting from pulsed irradiation of NCl3 at 248 and 308 nm were collected and analyzed.Two distinct spectral features were observed, one a long series of bands separated by 320 +/- 30 cm-1, the second an unresolved emission underlying the bands.The two features exhibit different time behavior and lifetimes in the limit of zero pressure.The photochemistry is interpreted via a model which involves the interaction of three electronic states of NCl3.
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