Nitrogen trichloride

Base Information

• Chemical Name: Nitrogen trichloride
• CAS No.: 10025-85-1
• Molecular Formula: Cl3N
• Molecular Weight: 120.366
• European Community (EC) Number: 233-045-1
• UNII: VA681HRW8W
• DSSTox Substance ID: DTXSID4074938
• Nikkaji Number: J96.482D
• Wikipedia: Nitrogen trichloride
• Wikidata: Q409473
• Mol file: 10025-85-1.mol

Synonyms:nitrogen chloride;nitrogen trichloride;trichloramine

Chemical Property of Nitrogen trichloride

Chemical Property:

• Appearance/Colour: Yellow oily liquid
• Vapor Pressure: 131mmHg at 25°C
• Melting Point: -40 °C (233 K)
• Boiling Point: 70 °C at 760 mmHg
• PKA: -22.67±0.70(Predicted)
• Flash Point: °C
• PSA: 3.24000
• Density: 1.72 g/cm³
• LogP: 1.74980
• Water Solubility.: insoluble H2O, decomposes in H2O after 24h; soluble CS2, phosphorus trichloride, benzene, CCl4, CHCl3 [MER06]
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 118.909632
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

99%, ^*data from raw suppliers

TRICHLORINE NITRIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Explodes when heated to approximately 200F (93C) or when exposed to direct sunlight. Toxic by ingestion and inhalation, strong irritant.
• Hazard Codes: Explodes when heated to approximately 200F (93C) or when exposed to direct sunlight. Toxic by ingestion and inhalation, strong irritant.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Other Nitrogen Compounds
• Canonical SMILES: N(Cl)(Cl)Cl
• Physical properties: Yellow, oily, heavy liquid; pungent odor; density 1.653 g/mL; freezes to rhombohedral crystalline solid below -40°C; evaporates in air rapidly; vaporpressure 150 torr at 20°C; explodes when heated at 93°C; highly unstable, decomposes explosively in light; insoluble in water, decomposes slowly in cold water after several hours; decomposes in hot water; soluble in benzene, chloroform, carbon tetrachloride, carbon disulfide and phosphorus trichloride.
• Uses: Bleaching of flour; wastage control of citrus fruit.

Technology Process of Nitrogen trichloride

There total 95 articles about Nitrogen trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

calcium hypochlorite (7778-54-3) + ammonium chloride (12125-02-9) → nitrogen trichloride (10025-85-1)

Guidance literature:

With hydrogenchloride; In dichloromethane; water; at 4 ℃; for 0.75h;

Reference yield:

ammonium chloride → nitrogen trichloride (10025-85-1) + perchlorate(1-) (14797-73-0,1059018-91-5)

Guidance literature:

In water; Electrolysis;

Reference yield:

nitrosylchloride (2696-92-6) → nitrosoamine (81390-26-3,35576-91-1,81407-93-4) + nitrogen trichloride (10025-85-1)

Guidance literature:

With ammonia; In neat (no solvent); reaction of NOCl with melted NH3;;

upstream raw materials:

calcium hypochlorite

ammonium chloride

nitrosylchloride

phosphorus pentachloride

Downstream raw materials:

iodic acid

iodine trichloride

iodine

nitrosylchloride

Refernces

• 1、 Noyes, W. A.. "". . p. 767 - 767. Retrieved 1913.
• 2、 Noyes, W. A.,Lyon. "". . p. 460 - 460. Retrieved 1901.
• 3、 Knothe,Hasenpusch. "Formation of Explosive Chlorine-Nitrogen Compounds during the Reaction of Ammonium Compounds with Chlorine". . p. 4529 - 4530. Retrieved 1996.
• 4、 Gershanovich,Gilbert. "Energetics of halogen amine reactions with triplet metastables: NFCl2 with Ar(3P0,2), He(23S), and N2(3Σ+u) and NCl3 with Ar(3P0,2)". . p. 840 - 848. Retrieved 1997.
• 5、 Sawodny, Wolfgang,Haertner, Heinz,Minkwitz, Rolf,Bernstein, Dirk. "VIBRATIONAL SPECTRA AND FORCE CONSTANTS FOR THE MOLECULAR SERIES NH3-nCln". . p. 145 - 154. Retrieved 1989.
• 6、 Chapin, R. M.. "". . p. 2112 - 211. Retrieved 1929.
• 7、 Fehér, Péter Pál,Purgel, Mihály,Lengyel, Adrienn,Stirling, András,Fábián, István. "The mechanism of monochloramine disproportionation under acidic conditions". . p. 16713 - 16721. Retrieved 2019.
• 8、 Noyes, W. A.. "". . p. 2159 - 2164. Retrieved 1925.
• 9、 Gilbert, J. V.,Wu, X. L.,Stedman, D. H.,Coombe, R. D.. "Photolysis of Nitrogen Trichloride". . p. 4265 - 4269. Retrieved 1987.
• 10、 -. "Diamondoid derivatives possessing therapeutic activity in the treatment of neurologic disorders". Page/Page column 25. . Retrieved 2008/06/13.