Macro Rings. 49. Use of Transannular Reactions to Add Bridges to Paracyclophane

DOI: 10.1021/jo01308a005

Source and publish data:

Journal of Organic Chemistry p. 3974 - 3981 (1980)

Update date:2022-08-31

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Authors:

Truesdale, E.A.

Cram, Donald J.

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Article abstract of DOI:10.1021/jo01308a005

New transannular reactions were used to introduce additional bridges into <2.2>paracyclophane (1).With CH2O-HCl, 4-acetyl<2.2>paracyclophane (3) gave (55percent) 4-acetyl-13-(chloromethyl)<2.2>paracyclophane (4), whose substituents are pseudogem to one an

Full text of DOI:10.1021/jo01308a005

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