Tetrahedron Letters p. 5700 - 5702 (2016)
Update date:2022-08-12
Topics:
Zhuang, Yan-Jun
Liu, Jie
Kang, Yan-Biao
Tin or gallium chloride catalyzed transformation of oximes or aldehydes to nitriles is described. Various nitriles were obtained in up to 99% of yields. The gram-scale reaction or the optically active dinitrile was also available. This synthetically useful method has avoided toxic organic or inorganic cyanides as well as transition or noble metal catalysts.
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