Pair-Selective Coupling of Alkynes with Alkenes on Zirconocene Complex

DOI: 10.1246/cl.1993.1001

Source and publish data:

Chemistry Letters p. 1001 - 1004 (1993)

Update date:2022-08-16

Topics:

Authors:

Takahashi, Tamotsu

Xi, Zhenfeng

Rousset, Christophe J.

Suzuki, Noriyuki

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Article abstract of DOI:10.1246/cl.1993.1001

When ethylene and alkynes such as 4-octyne and diphenylacetylene were treated with Cp2ZrBu2, highly pair selective coupling products were formed in high yields.Similarly, styrene or trimethylvinylsilane also afforded cross coupling products with alkynes on zirconocene complex.

Full text of DOI:10.1246/cl.1993.1001

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